ECS White Paper: BMPs for High Nitrogen Feedstocks

ECS White Paper ECS Staff 07/30/2021

By Tim O’Neill & Geoff Hill

High nitrogen feedstocks include biosolids, digestate, and food waste. These feedstocks are often in abundant supply but are challenging to process with rudimentary processes like static piles or windrows due to their tendency to off-gas ammonia or remain in their anoxic state dominated by smelly anaerobic microbiology. This whitepaper outlines the steps necessary to get these challenging feedstocks into a BMP mix that can be maintained in aerobic conditions to minimize odor release and maximize decomposition rate.

1.0 OVERVIEW: BMPS AND KPIS

There are a few simple Best Management Practices (BMPs) that can be regularly performed onsite at any composting facility and used as Key Performance Indicators(KPIs). With regular collection and an understanding of the target and range within each BMP, site operators can use the data to make immediate changes, predict emissions, and understand end product quality. The most effective times to collect data and adhere to BMPs (and use these as KPIs) is on the mix going into primary composting and during the primary composting process. This short paper provides our recommendations for BMP data collection at these two stages and a short explanation of why these parameters are critical.

2.0 INITIAL BMP MIX

A BMP mix is critical to the entire compost process. There are three key measurable parameters in a BMP mix: moisture, density, and C/N ratio. Since ground woody amendments are generally

with high nitrogen residual feedstocks (such as biosolids, manures, and digestate) a fourth qualitative parameter is “mix uniformity.” These parameters set the stage for conditions on the biofilm where the decomposition takes place.

Conditions For Composting

If all are within BMP ranges, the subsequent composting process will have the greatest chance of proceeding under optimal process conditions. If one or more parameters falls outside the BMP range, the process will become inhibited due to anoxic / anaerobic conditions (poor gas exchange) or excess ammonia (low C/N) resulting in the generation of strong ammonia odor and dramatically slower bio-stabilization.

3.0 BMP MIX – RECOMMENDATIONS

The table below outlines the three mix parameters we think should be measured and logged regularly to provide assurance that a BMP mix is being made each and every batch of compost.

Key Process VariableBMP TargetMethodFrequency
Bulk Density750-950 lb/cyBucket and scale Composite sample each batch
Moisture ContentMoist not drippySqueeze test3-4 Grab samples each batch
Moisture Content52-63%Lab test to verify squeeze testQuarterly
C/N ratio>25Lab testQuarterly

4.0 THE BUCKET AND SCALE TEST METHOD

  • Find a standard 5 gallon bucket and mark the height of the bucket at the 5 gallon level.
  • Tare the bucket weight on the ECS provided scale.
  • Fill the bucket to 1/3 level with grab samples of compost taken from below the surface.
  • Drop the bucket from 1’ height to a hard surface.
  • Repeat at 2/3 full level.
  • Fill to 3/3 level (don’t drop it) and weigh the full bucket.
  • Multiply the weight of the compost x40 to obtain density in pounds per cubic yard and log the data.

5.0 Overview of BMP Conditions During Active Composting

While the production of a BMP compliant mix requires the operator’s attention, the sustaining BMP
oxygen and temperature levels during active composting is largely dependent on the design of the aeration and control system. Consistently maintaining BMP conditions requires feedback-controlled aeration that automatically adjusts to meet the highly variable cooling demands of the biological process and achieve user defined process goals (such as PFRP). Further, the mechanical design of the aeration system must provide adequate peak flow rates (for cooling) and flow uniformly to keep the majority of composting volume within the BMP temperature and oxygen ranges. The peak design flow should be matched to the degradability of the feedstock mix; airflow rates between 5 – 10 cfm/cy of mix can be periodically required early in the composting cycle. Windrow composting airflow rates are generally less than 0.1 cfm/cy. Fabric covered systems usually restrict airflow rates to less than 1 cfm/cy.

Control The Ammonia Gas

Ammonia inhibition is common place in biosolids composing despite being quite easy to control and prevent. Both pH and temperature act as forces driving ammonium (NH4+) into free ammonia gas (NH3).

Uncontrolled, the process can be severely impacted by free ammonia gas, dissolved into the liquid of the biofilm of each compost particle, and the process can be inhibited by its own toxicity (ammonia gas is toxic). However, with good temperature control and woody bulking agent to offset the alkaline pH of biosolids, the majority of ammonium can be kept in ionized form (NH4+) where it is available to bacteria for cellular growth and oxidation of carbon compounds. Figure 2 displays the relationships between ammonium and ammonia as affected by pH and temperature. A process at 50°C and pH 8.3 can have <50% of its nitrogen in ammonia gas phase, whereas that same process at 80°C would have >85% of its nitrogen in ammonia gas, be highly odorous, and could be severely rate limited.

The Effect Of Temperature On Commercial Composting

High temperatures have been shown to inhibit the general (non-feedstock specific) composting in two ways. First, is the fact that bio-oxidative process has been shown to roughly increase by a factor of 2x up to around 65°C, and then drop off sharply at higher temperatures due to temperature inhibition.

Second, is due to the inverse relationship between temperature and oxygen solubility in the liquid film layer. The explanation is as follows: each composting particle is covered in a thin water layer, or biofilm, as shown in Figure 1. The combination of oxygen concentration in the air space and the temperature in the biofilm determine the amount of oxygen that the biofilm can carry (this relationship is shown in Figure 3 published by the UK Environment Agency). The aerobic bacteria that do the composting reside in the biofilm. High dissolved oxygen levels (>3.5ppm) have been shown to provide rapid stabilization (conversion of bio-available solids to CO2) and low odor production.

Photo of Finished Compost from Food and Yard Waste Using High Aeration
Finished Compost from Food and Yard Waste Using High Aeration